1-Diisopropylaminophospholes: synthesis and X-ray characterisations of new palladium and platinum complexes

Autor:	Maryse Gouygou, Gilbert G. A. Balavoine, Jérôme Hydrio, Jean-Claude Daran, Frédéric Dallemer
Rok vydání:	2002
Předmět:	Stereochemistry Chemistry Organic Chemistry Phosphole X-ray chemistry.chemical_element Biochemistry Inorganic Chemistry chemistry.chemical_compound Crystallography Materials Chemistry Physical and Theoretical Chemistry Platinum Cis–trans isomerism Palladium
Zdroj:	Journal of Organometallic Chemistry. :19-26
ISSN:	0022-328X
Popis:	Starting from palladium precursor [Pd(CH3CN)2Cl2], 1-diisopropylaminophospholes give dinuclear complexes, [Pd(phosphole)Cl2]2, which proved to be intermediates in the formation of mononuclear complexes, cis-[Pd(phosphole)2Cl2]. In contrast with the platinum precursor, only mononuclear complexes, [Pt(phosphole)2Cl2], are obtained with both cis and trans configurations. These new complexes were fully characterised by X-ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0456dd5fee6a9e66a84189c7e05acbea https://doi.org/10.1016/s0022-328x(01)01145-7 Zobrazit plný text záznamu Full Text from ScienceDirect