Electrochemical reduction of N-nitroaminotetrazoles
Autor: | V. N. Leibzon, A. G. Mayants, S. S. Gordeichuk |
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Rok vydání: | 1992 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 28:785-787 |
ISSN: | 1573-8353 0009-3122 |
DOI: | 10.1007/bf00474493 |
Popis: | The electrochemical reduction of 5-nitroamino- and 2-methyl-5-nitroaminotetrazoles at the first wave potential consumes six electrons, while the reduction at the second wave potential consumes eight or nine electrons. The preparative reduction of 2-methyl-5-nitroaminotetrazole at the second wave potential leads to 2-methyl-5-aminotetrazole and ammonia. A mechanism is proposed for these reactions. |
Databáze: | OpenAIRE |
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