Crystal Structures and Luminescence Properties of Pd(II) and Pt(II) Complexes with 2,5-Bis(thiophene)-1-nonyl-3,4-bis(methylthio)pyrrole

Autor: Min-Kook Nah, Jun-Gill Kang, In Tae Kim, Sang Woo Lee, Dong-Hee Cho, Changmoon Park, Young-Ju Bae, Young Jin Park, Sung-Il Oh, Tack-Han Woo
Rok vydání: 2009
Předmět:
Zdroj: Bulletin of the Korean Chemical Society. 30:1157-1163
ISSN: 0253-2964
DOI: 10.5012/bkcs.2009.30.5.1157
Popis: oto the pyrrole frame. The luminescence properties of the free ligand and the complexes were investigated in solution and solid states. The luminescence of the compounds were not favored by substituting thiophene moieties to the pyrrole frame, compared to the unsubstituted nbmptp (nbmptp = 1-nonyl-3,4-bis(methylthio)pyrrole). In particular, thiophene substitution quenched the emission from the complexes dissolved in CH2Cl2 and reduced the charge transfer transitions from S atoms of the thio moieties to Pt in crystalline state, which was very characteristic of Pt(nbmptp)Cl2.
Databáze: OpenAIRE