Bond length-reactivity correlations for sulfate monoesters. The crystal structure of potassium 4-nitrophenyl sulfate, C6H4KNO6S
| Autor: | Faruk Nome, Jacks P. Priebe, Tiago A. S. Brandão, Amanda S. Damasceno, Adailton J. Bortoluzzi, Anthony J. Kirby |
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| Rok vydání: | 2005 |
| Předmět: |
chemistry.chemical_classification
Chemistry Potassium Organic Chemistry Inorganic chemistry Ionic bonding Salt (chemistry) chemistry.chemical_element Crystal structure Analytical Chemistry Inorganic Chemistry Bond length Crystallography chemistry.chemical_compound Orthorhombic crystal system Reactivity (chemistry) Sulfate Spectroscopy |
| Zdroj: | Journal of Molecular Structure. 734:205-209 |
| ISSN: | 0022-2860 |
| Popis: | Potassium 4-nitrophenyl sulfate, C6H4KNO6S, crystallizes in the orthorhombic system, Pbca space group, with cell parameters: a=6.990(1), b=13.130(1), c=19.180(1) A, V=1760.3(3) A3. The asymmetric unit consists of a discrete ionic pair of the salt. The packing shows the K+ ion surrounded by eight oxygen atoms from six different p-nitrophenyl sulfate anions. In addition, the structure–structure and structure–reactivity correlations relevant to sulfate transfer process are discussed. |
| Databáze: | OpenAIRE |
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