Bimolecular relaxation kinetics observed in radiation-optical properties of Ge–As(Sb)–S glasses
| Autor: | Oleh Shpotyuk, H. Altenburg, V. Balitska |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
Chemistry
Chalcogenide Coordination number Mineralogy Thermodynamics Radiation Condensed Matter Physics Electronic Optical and Magnetic Materials chemistry.chemical_compound Materials Chemistry Ceramics and Composites Relaxation (physics) Spectroscopy Ternary operation Chemical composition Stoichiometry |
| Zdroj: | Journal of Non-Crystalline Solids. 352:4809-4813 |
| ISSN: | 0022-3093 |
| Popis: | Numerical parameters of decaying bimolecular relaxation kinetics are analysed for radiation-optical properties of chalcogenide glasses within ternary stoichiometric As 2 S 3 –GeS 2 and Sb 2 S 3 –GeS 2 as well as non-stoichiometric As 2 S 3 –Ge 2 S 3 systems in dependence on their composition. It is shown, that the observed compositional dependences of bimolecular relaxation parameters have a monotonic character in the glasses of both stoichiometric systems, while the anomalous extremum-like behavior is observed in the vicinity of average coordination number close to 2.7 in non-stoichiometric glasses. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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