Amides as Weak Coordinating Groups in Proximal C-H Bond Activation

Autor:	Manmohan Kapur, Riki Das, Gangam Srikanth Kumar
Rok vydání:	2017
Předmět:	C h bond 010405 organic chemistry Chemistry Stereochemistry Site selectivity Organic Chemistry Regioselectivity Metallacycle 010402 general chemistry 01 natural sciences 0104 chemical sciences Proximal site Reactivity (chemistry) Physical and Theoretical Chemistry
Zdroj:	European Journal of Organic Chemistry. 2017:5439-5459
ISSN:	1434-193X
DOI:	10.1002/ejoc.201700546
Popis:	Site selectivity is an inherent challenge in C–H functionalization reactions. The most intensively sought-after approaches have involved the employment of Lewis-basic coordinating groups to direct a metal to a proximal site, in the process generating a metallacycle capable of further organometallic reactivity. In the recent years considerable effort has been directed towards the development of new transformations involving transition-metal-mediated C–H functionalization directed by weakly coordinating groups. This microreview focuses on the role and utility of amides and anilides in directed, proximal C–H bond functionalization reactions.
Databáze:	OpenAIRE
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