Interaction between nanocluster polyoxometallates and low-molecular-weight organic compounds

Autor:	E. V. Eremina, A. A. Ostroushko, L. V. Adamova, K. V. Grzhegorzhevskii
Rok vydání:	2015
Předmět:	Standard molar entropy Inorganic chemistry Kinetics Sorption chemistry.chemical_compound symbols.namesake chemistry symbols Methanol Physical and Theoretical Chemistry Porosity Spectroscopy Raman spectroscopy Benzene
Zdroj:	Russian Journal of Physical Chemistry A. 89:1439-1444
ISSN:	1531-863X 0036-0244
DOI:	10.1134/s0036024415080245
Popis:	The equilibrium sorption of methanol and benzene vapors by spherical porous nanocluster polyoxometallates with keplerate structures of different compositions (Mo132 and Mo72Fe30) and polyoxometallate (Mo138) with a toroidal structure and patterns in the kinetics of these processes are studied. Changes in the chemical potentials of the sorbates and polyoxometallates, specific Gibbs energies of the interaction of the polyoxometallates with the indicated substances, and the partial molar entropy of the interaction of Mo132 with methanol are calculated. The stability of the polyoxometallate structure in the sorbate vapors is studied via IR and Raman spectroscopy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::03b76fa7ace334ed0a651967981c557d https://doi.org/10.1134/s0036024415080245 Zobrazit plný text záznamu Full text from SpringerLink