Steam gasification of poultry litter biochar for bio-syngas production

Autor: Christian Manera, Janaína Junges, Patrícia Poletto, Danielle Restelatto, Aline Dettmer, Daniele Perondi, Jayna Pessuto Silva, Marcelo Godinho, Gabriela Carvalho Collazzo, Antônio C. F. Vilela
Rok vydání: 2017
Předmět:
Zdroj: Process Safety and Environmental Protection. 109:478-488
ISSN: 0957-5820
DOI: 10.1016/j.psep.2017.04.029
Popis: Poultry litter, the major waste generated by poultry farming, has its main use in soil as a fertilizer. However, the uncontrolled use of poultry litter for this purpose can result in environmental impacts such as the emission of methane, a greenhouse gas. Therefore, the thermochemical conversion of this waste can be a solution to this problem, since its products can be converted into useful energy. In this work, pyrolysis experiments were conducted in a tubular reactor, using N 2 atmosphere and a final temperature of 800 °C. Furthermore, the steam gasification of poultry litter biochar obtained in the pyrolysis experiments was investigated in a fixed-bed tubular reactor at different temperatures (800, 850 and 900 °C). The maximum hydrogen (H 2 ) reaction rates were observed in the first 15 min of the reaction, and there was a change in the maximum reaction rate towards lower reaction times with increased temperature. The elevated H 2 yield may be associated with metals present in the biochar, especially potassium (K). Bio-syngas (H 2 + CO) obtained from steam gasification of poultry litter biochar presented high potential to reduce iron ore by indirect reduction (IR) in blast furnaces (BF), or in direct reduced iron (DRI) processes.
Databáze: OpenAIRE