Copper salt–assisted polymerization of bispropargyl ether–bismaleimide blend
| Autor: | Chinnaswamy Thangavel Vijayakumar, J Dhanalakshmi |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
010407 polymers
Materials science Polymers and Plastics Ether 02 engineering and technology 021001 nanoscience & nanotechnology Copper sulphate pentahydrate 01 natural sciences Methane 0104 chemical sciences chemistry.chemical_compound chemistry Polymerization Copper salt Materials Chemistry 0210 nano-technology Nuclear chemistry |
| Zdroj: | Journal of Elastomers & Plastics. 51:52-63 |
| ISSN: | 1530-8006 0095-2443 |
| DOI: | 10.1177/0095244318769952 |
| Popis: | Bispropargyl ether (BPE) of bisphenol-A was prepared. It was blended with 4,4’-bismaleimido diphenyl methane (BMI, 0.5:0.5 mol). The copper sulphate pentahydrate (CuSO4·5H2O) was blended (1% w/w) separately with pure BPE and BPE-BMI blend and the materials were thermally cured. The structural characterization of the materials was done using a Fourier-transform infrared spectrophotometer. The curing behaviour of the materials was investigated using differential scanning calorimetry. The presence of copper salt in BPE shifted the curing temperature to lower temperature region. The presence of copper salt in BPE-BMI blend also decreased the curing onset temperature by approximately 15°C. The thermal property of the polymers was investigated using thermogravimetry. The incorporation of copper salt in BPE-BMI blend led to polymer with increased thermal stability. |
| Databáze: | OpenAIRE |
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