Pyridinium ionic liquids-accelerated amine-catalyzed Morita–Baylis–Hillman reaction
| Autor: | San-Hu Zhao, Zhao-Bin Chen, Li-Heng Feng, Hai-Rong Zhang |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
chemistry.chemical_classification
Tertiary amine Pyridinium Compounds Process Chemistry and Technology DABCO Aldehyde Catalysis chemistry.chemical_compound chemistry Ionic liquid Polymer chemistry Organic chemistry Baylis–Hillman reaction Pyridinium Physical and Theoretical Chemistry Hexamethylenetetramine |
| Zdroj: | Journal of Molecular Catalysis A: Chemical. 258:251-256 |
| ISSN: | 1381-1169 |
| DOI: | 10.1016/j.molcata.2006.05.032 |
| Popis: | Several ionic liquids were used for Morita–Baylis–Hillman reaction; the results show that the pyridinium ionic liquids N-ethylpyridinium tetrafluoroborate ([EPy][BF4]) and N-butylpyridinium nitrate ([BuPy][NO3]) as reaction media were efficient for DABCO-catalyzed Morita–Baylis–Hillman reaction. In short reaction time, good yields have been obtained. In addition, in the presence of ionic liquid [EPy][BF4], the hexamethylenetetramine (HMTA), a cheap tertiary amine, effectively catalyzed the Morita–Baylis–Hillman reaction. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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