The selective functionalization of saturated hydrocarbons. Part 33. Further reactions which take place in the FeII-FeIV manifold

Autor:	Béatrice M. Chabot, Derek H. R. Barton
Rok vydání:	1996
Předmět:	Diphenyl disulfide chemistry.chemical_classification Ligand Thiophenol Carboxylic acid Organic Chemistry Photochemistry Biochemistry Sodium sulfide chemistry.chemical_compound chemistry Selenide Drug Discovery Polymer chemistry Diphenyl diselenide Alkyl
Zdroj:	Tetrahedron. 52:10287-10300
ISSN:	0040-4020
DOI:	10.1016/0040-4020(96)00564-9
Popis:	Utilization of the FeII-H2O2 system in the presence of diphenyl diselenide, phenylselenol, diphenyl disulfide and thiophenol converts saturated hydrocarbons into the corresponding alkyl phenyl selenide or alkyl phenyl sulfide. Starting with FeIII-H2O2 no reaction occurs in presence of diphenyl diselenide but the GifIV system (FeII/O2) is able to produce phenyl seleno derivatives along with the oxidation products. The presence of sodium sulfide with the FeII and FeIII-H2O2 systems affords some dicyclohexyl disulfide. Mechanistic studies suggest than all these reaction are based on the FeII-FeIV manifold with a suitable carboxylic acid as ligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::03757ce1d0ddcca924f9a354f962ce8c https://doi.org/10.1016/0040-4020(96)00564-9 Zobrazit plný text záznamu Full Text from ScienceDirect