Clathrate formation and phase transitions in ?-hydroquinone

Autor: A. A. Vlasova, V. E. Schneider, Evaldas E. Tornau, A. A. Gurskas
Rok vydání: 1985
Předmět:
Zdroj: Journal of Inclusion Phenomena. 3:235-242
ISSN: 1573-1111
0167-7861
DOI: 10.1007/bf00655727
Popis: Clathrate thermodynamic stability conditions and the phase transitions associated with either the orientational ordering of the guest molecules or with the condensation of the guest molecules in the host lattice are investigated by means of the common microscopic model. The theory proposed describes the thermodynamic properties of β-hydroquinone (Qβ) clathrates. The dielectric constant e(T) was measured experimentally inQβ·CH3OH andQβ·SO2 in the temperature range from 4.2 to 300 K and the phase transitions were found. It is shown that the theory qualitatively explains the experimental data obtained.
Databáze: OpenAIRE