Spin trapping azidyl (N3•), cyanatyl (OCN•), cyanyl (•CN) radicals, and chlorine atom (Cl•)

Autor:	Edward G. Janzen, Paul B. McCay, Dale E. Nutter, Henry N. Blount, J. Lee Poyer, Henry J. Stronks, Edward R. Davis
Rok vydání:	1980
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Spin trapping Chemistry Radical Organic Chemistry Chlorine atom General Chemistry Azide Cyanate Photochemistry Catalysis Nitrone
Zdroj:	Canadian Journal of Chemistry. 58:1596-1598
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v80-252
Popis:	Azidyl, cyanatyl, and cyanyl radicals and chlorine atoms have been detected by spin trapping using α-phenyl N-tert-butyl nitrone (PBN) in the monoelectronic electrooxidations of azide, cyanate, cyanide, and chloride. Azidyl and cyanatyl radicals were also detected with PBN in the persulfate oxidations of azide and cyanate. Azidyl radicals could be detected in the reaction of azide with hydroxyl radicals in the presence of PBN.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0348a4f504f313e43e29c7d6421ecd27 https://doi.org/10.1139/v80-252 Zobrazit plný text záznamu