Novel Rearrangement of Spirophosphoranes

Autor:	P. P. Onys'ko, Y. G. Vlasenko, Anatoly D. Synytsya, Andrii V. Bezdudny, Yu. V. Rassukana, Alexander N. Chernega, S. V. Lobanov
Rok vydání:	2013
Předmět:	Chemistry Stereochemistry Organic Chemistry Ring (chemistry) Biochemistry Chloride Medicinal chemistry Cycloaddition Inorganic Chemistry Aminophosphonate Acid catalyzed medicine Stereoselectivity medicine.drug
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 188:173-175
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426507.2012.743546
Popis:	Reactions of N-trifluoroacetyl trifluoroacetimidoyl chloride with acyclic or cyclic phosphites proceed by the cheletropic 1,4-cycloaddition scheme to form mono- or spirocyclic phosphoranes. The spirophosphorane resulting from the reaction with diethylamino-o- phenylenedioxyphosphite undergoes unusual acid catalyzed stereoselective rearrangement involving ring expansion to afford functionalized cyclic aminophosphonate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0331abcb05d677564ccdb364cb5ee952 https://doi.org/10.1080/10426507.2012.743546 Zobrazit plný text záznamu