A new method for the synthesis of sulfonated polynaphthylimides

Autor:	Yu. A. Dobrovol’skii, M. G. Bugaenko, Mikhail D. Dutov, Svyatoslav A. Shevelev, Olga V. Serushkina, A. V. Pisareva, A. L. Rusanov, E. G. Bulycheva
Rok vydání:	2013
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Condensation polymer Polymers and Plastics chemistry Sulfide Polymer chemistry Materials Chemistry Ceramics and Composites Organic chemistry Polymer Hydrogen peroxide
Zdroj:	Polymer Science Series B. 55:478-483
ISSN:	1555-6123 1560-0904
DOI:	10.1134/s1560090413070026
Popis:	A new method for the synthesis of sulfonated polynaphthylimides has been developed on the basis of the postsulfonation of high-molecular-mass polynaphthylimides with a sulfuric acid-oleum mixture. Sulfonated polymers of this type have been obtained from the polycondensation products of 5-phenylthiophenylene-1,3-diamine with dianhydrides of 1,4,5,8-naphthalenetetracarboxylic acid and 4,4′-(1,4-phenylenedicarbonyl)-bis-naphthalene-1,8-dicarboxylic acid. It has been shown that hydrogen peroxide oxidation of sulfide bridge groups of these polymers in an acidic medium yields high-molecular-mass compounds that contain sulfonic bridge fragments and, therefore, have increased thermal stabilities and enhanced proton conductivities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::03304a89b2a4e3d0d146a6402b91fb30 https://doi.org/10.1134/s1560090413070026 Zobrazit plný text záznamu Full text from SpringerLink