Crystal structure and IR spectroscopic study of (CN3H6)2[(UO2)2(C2O4)(CH3COO)4]

Autor:	Larisa B. Serezhkina, Eugenia V. Peresypkina, Victor N. Serezhkin, N. A. Neklyudova, A. V. Virovets
Rok vydání:	2013
Předmět:	Hydrogen bond Inorganic chemistry Infrared spectroscopy Space group General Chemistry Crystal structure Condensed Matter Physics Uranyl Oxalate chemistry.chemical_compound Crystallography chemistry X-ray crystallography General Materials Science Hexagonal bipyramid
Zdroj:	Crystallography Reports. 58:275-279
ISSN:	1562-689X 1063-7745
Popis:	Compound (CN3H6)2[(UO2)2(C2O4)(CH3COO)4] is synthesized and characterized by IR spectroscopy and single-crystal X-ray diffraction [a = 8.5264(2) A, b = 13.8438(4) A, c = 10.7284(2) A, β = 103.543(1)°, space group P21/n, Z = 2, and R = 0.0258]. The main structural units of the crystals are binuclear [(UO2)2C2O4(CH3COO)4]2− groups, which belong to the A2K02B401 crystal chemical group of uranyl complexes (A = UO22+, K02 = C2O42−, and B01 = CH3COO−). The coordination polyhedron of the uranium atom is the UO8 hexagonal bipyramid with the oxygen atoms of the uranyl ion at the axial positions. Uranium-containing groups and guanidinium cations are connected by electrostatic interactions and by the hydrogen bond system, which involves hydrogen atoms of guanidinium cations and oxygen atoms of oxalate and acetate anions. The results of the spectroscopic study of the compound agree with the X-ray diffraction data.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0304fedd0e00136357916b48cc75b4d9 https://doi.org/10.1134/s1063774513020235 Zobrazit plný text záznamu Plný text ve formátu PDF