Radical Superexchange in Semiquinone Complexes Containing Diamagnetic Metal Ions. 3,6-Di-tert-butyl-1,2-semiquinoate Complexes of Zinc(II), Cobalt(III), Gallium(III), and Aluminum(III)

Autor:	Christopher W. Lange, Brenda J. Conklin, Cortlandt G. Pierpont
Rok vydání:	1994
Předmět:	Semiquinone Metal ions in aqueous solution Inorganic chemistry chemistry.chemical_element Crystal structure Zinc Inorganic Chemistry Crystallography chemistry Superexchange Physical and Theoretical Chemistry Gallium Cobalt Monoclinic crystal system
Zdroj:	Inorganic Chemistry. 33:1276-1283
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00085a012
Popis:	The tris(3,6-di-tert-butylsemiquinonato)gallium(III), -aluminum(III), and -cobalt(III) complexes have been studied structurally, spectrally, and magnetically. Complexes of the three diamagnetic metals have octahedral structures of D 3 symmetry (Ga(3,6-DBSQ) 3 , monoclinic, C2/c, a=22.069(6) A, b=19.365(5) A, c=10.163(3) A, β=94.90(2) o , V=4327(2) A 3 , Z=4; Co(3,6-DBSQ) 3 , monoclinic, C2/c, a=21.799(6) A, b=19.376(8) A, c=10.167(3) A, β=94.99(3) o , V=4278(3) A 3 , Z=4
Databáze:	OpenAIRE
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