Infrared and Raman spectra and vibrational assignments for 4-(dimethylamino)benzaldehyde and its zinc complex

Autor:	James Rosencrance, Paul W. Jagodzinski
Rok vydání:	1986
Předmět:	chemistry.chemical_classification Infrared Ligand Stereochemistry General Engineering chemistry.chemical_element Zinc Benzaldehyde symbols.namesake chemistry.chemical_compound Crystallography chemistry Normal mode symbols Molecule Raman spectroscopy Inorganic compound
Zdroj:	Spectrochimica Acta Part A: Molecular Spectroscopy. 42:869-879
ISSN:	0584-8539
DOI:	10.1016/0584-8539(86)80205-7
Popis:	The vibrational spectra of 4-(dimethylamino)benzaldehyde (DABA) and its zinc complex are presented and vibrational assignments are proposed. Significant differences between the spectra of the parent molecule and the complex are observed. Examination of the form of the normal modes facilitates explanation of proposed frequency shifts of ring modes upon complexation. The spectra of the complex are interpreted by employing a quinonoid-type structure for the DABA ligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::029cf12e50cf529be4eac25349a9f7d0 https://doi.org/10.1016/0584-8539(86)80205-7 Zobrazit plný text záznamu