C1 Coupling via bromine activation and tandem catalytic condensation and neutralization over CaO/zeolite compositesElectronic supplementary information (ESI) available: additional figures. See http://www.rsc.org/suppdata/cc/b3/b314118g
| Autor: | Galen D. Stucky, Ivan M. Lorkovic, Peter C. Ford, Eric W. McFarland, Maria L. Noy, Mike Weiss, Jeffrey H. Sherman |
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| Rok vydání: | 2004 |
| Předmět: |
Bromomethane
Bromine Chloromethane Inorganic chemistry Condensation Metals and Alloys Oxide chemistry.chemical_element General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Methanol Zeolite |
| Zdroj: | Chemical Communications. :566 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/b314118g |
| Popis: | We demonstrate here an alternative scheme for C1 coupling by way of methane bromination, followed by concurrent bromomethane condensation and quantitative HBr neutralization; regeneration of the metal oxide with O2 with recovery of Br2 completes the cycle. |
| Databáze: | OpenAIRE |
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