Spectroscopic investigation of the constituent components effect on the biodegradable package characteristics

Autor: N. Cioica, Onuc Cozar, M. Todica, Radu Fechete, Constantin Coţa, E. M. Nagy, Claudiu Filip
Rok vydání: 2015
Předmět:
Zdroj: AIP Conference Proceedings.
ISSN: 0094-243X
DOI: 10.1063/1.4938437
Popis: The effect of the nature and the content of the plasticizers (water, glycerol) on the corn starch based biodegradable packages properties (crystalline-amorphous) and also on their degradation process after absorption of distilled water were investigated by 1H NMR relaxation and 13C CP/MAS NMR spectroscopies. For this goal, a set of 14 samples with various starch/glycerol/water (mass %) ratios were prepared and investigated after extrusion process in order to establish their crystalline or amorphous character. The composition having starch/glycerol/water 68/17/15 mass % ratio was found to have a dominant amorphous character and very similar features with a commercial specimen (USA) used for the package. It was also found that this best package is extremely degraded after just one day under water absorption. The most resistant package was that with a large content of starch (78/19.5/2.5).
Databáze: OpenAIRE