ChemInform Abstract: Chiral Silicon Lewis Acids Having a Pentacoordinate Stereogenic Silicon Center:29Si NMR Studies and Application to Asymmetric Diels-Alder Reactions

Autor:	Yuhsuke Sakaguchi, Yasuo Hatanaka, Tatsuya Minami, Tohru Sekikawa, Yuhki Iwade
Rok vydání:	2014
Předmět:	Silylation Silicon chemistry Stereochemistry Diels alder chemistry.chemical_element Center (algebra and category theory) General Medicine Lewis acids and bases Stereocenter
Zdroj:	ChemInform. 45
ISSN:	0931-7597
DOI:	10.1002/chin.201416034
Popis:	NMR Studies reveal that chiral pentacoordinate silyl triflimides derived from BINOL derivatives (I) with a silicon stereogenic center are highly configurationally unstable.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::02683b4e6fdbb6fbc50a197e3ee28d3b https://doi.org/10.1002/chin.201416034 Zobrazit plný text záznamu Plný text