Meso-Substituent Effects on Redox Properties of the 5,10-Porphodimethene-Type P,S,N2-Hybrid Calixphyrins and Their Metal Complexes

Autor:	Yoshihiro Matano, Tooru Miyajima, Masato Fujita, Hiroshi Imahori
Rok vydání:	2009
Předmět:	Trifluoromethyl Organic Chemistry Substituent chemistry.chemical_element Redox Rhodium Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Polymer chemistry visual_art.visual_art_medium Electronic effect Organic chemistry Physical and Theoretical Chemistry Palladium
Zdroj:	Organometallics. 28:6213-6217
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om900745t
Popis:	The 5,10-porphodimethene-type P,S,N2-hybrid calixphyrins bearing p-methoxyphenyl or p-(trifluoromethyl)phenyl groups at the sp2-hybridized meso carbons and their palladium(II) and rhodium(I) complexes were prepared and characterized. The electronic effects of the meso-aryl substituents on the redox properties of the π-conjugated subunits were evaluated for both the free bases and the palladium complexes, and the hemilabile nature of the P,S,N2-calixphyrin platforms in the rhodium complexes was revealed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0263416020fbdbffd6feafa9cfcff72f https://doi.org/10.1021/om900745t Zobrazit plný text záznamu