Strained alkyne polymers capable of SPAAC via ring-opening metathesis polymerization
| Autor: | Rajeshwar Vasdev, Kyle Classen, Joe B. Gilroy, Wilson Luo, Mark S. Workentin, Michael Anghel, Samantha Novoa |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics 010405 organic chemistry Organic Chemistry Alkyne Bioengineering Polymer 010402 general chemistry Metathesis 01 natural sciences Biochemistry Combinatorial chemistry 0104 chemical sciences chemistry Polymerization Ring-opening metathesis polymerisation |
| Zdroj: | Polymer Chemistry. 12:5542-5547 |
| ISSN: | 1759-9962 1759-9954 |
| Popis: | The incorporation of strained alkynes into polymers is generally achieved by employing step-growth polymerization methods or post-polymerization reactions. Here, we demonstrate that cyclopropenone-masked strained alkynes are tolerant to chain-growth ring-opening metathesis polymerization, and that, upon post-polymerization photochemical demasking with loss of CO, the strained alkyne group appended to each repeating unit can be used to prepare functional (e.g., fluorescent or redox-active) polymers from a common polymer backbone. We support our claims about polymer transformations throughout the manuscript through the inclusion of a complete set of model reactions and characterization data for analogous molecular species. The findings of this study are transferable to other polymeric systems, opening the door to the creation of libraries of multifunctional chain-growth polymers with identical polymer backbones. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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