ChemInform Abstract: Synthesis of N-Imidoyl and N-Oxoimidoyl Sulfoximines from 1-Alkynes, N-Sulfonyl Azides, and Sulfoximines

Autor:	Phil Ho Lee, Jaeeun Kim, Ki-Bbeum Kim, Wonseok Choi, Taekyu Ryu
Rok vydání:	2015
Předmět:	Sulfonyl chemistry.chemical_classification Chemistry General Medicine Medicinal chemistry
Zdroj:	ChemInform. 46
ISSN:	0931-7597
DOI:	10.1002/chin.201545104
Popis:	N-Imidoylation of sulfoximines is developed from a Cu-catalyzed three-component reaction from 1-alkynes, N-sulfonyl azides, and sulfoximines in THF at room temperature under air. In addition, N-oxoimidoylation of sulfoximines is accessed from a Cu-catalyzed three-component reaction from 1-alkynes, N-sulfonyl azides, and sulfoximines in THF at room temperature followed by a Cu-catalyzed oxidative reaction at 50 °C under air, producing N-oxoimidoyl sulfoximines.
Databáze:	OpenAIRE
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