Hydrogen production by steam reforming of dimethoxymethane over bifunctional CuO-ZnO/γ-Al 2 O 3 catalyst
| Autor: | V.D. Belyaev, A.A. Pechenkin, Sukhe D. Badmaev, Vladimir A. Sobyanin |
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| Rok vydání: | 2015 |
| Předmět: |
Atmospheric pressure
Hydrogen Renewable Energy Sustainability and the Environment Chemistry Inorganic chemistry Energy Engineering and Power Technology chemistry.chemical_element Condensed Matter Physics Catalysis Steam reforming chemistry.chemical_compound Fuel Technology Fuel cells Dimethoxymethane Bifunctional Hydrogen production |
| Zdroj: | International Journal of Hydrogen Energy. 40:14052-14057 |
| ISSN: | 0360-3199 |
| DOI: | 10.1016/j.ijhydene.2015.05.188 |
| Popis: | Dimethoxymethane steam reforming (DMM SR) to a hydrogen-rich gas over bifunctional СuO-ZnO/γ-Al 2 O 3 catalysts was studied. Complete DMM conversion was observed over 10wt.% СuO-5wt.% ZnO/γ-Al 2 O 3 catalyst under atmospheric pressure, T = 280–300 °C, GHSV = 10000 h −1 and H 2 O/DMM = 5 mol/mol with hydrogen productivity of ∼16.5 L H 2 /(g cat ·h). Based on the data on the performance of γ-Al 2 O 3 , CuO/γ-Al 2 O 3 and ZnO/γ-Al 2 O 3 under DMM SR conditions, the possible role of each catalyst component is discussed. |
| Databáze: | OpenAIRE |
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