SYNTHESIS OF THE FOUR POSSIBLE STEREOISOMERS OFN-2′-METHYLBUTYL-2-METHYLBUTYLAMIDE, THE SEX PHEROMONE OF THE LONGHORN BEETLEMIGDOLUS FRYANUSWESTWOOD

Autor:	Arlene G. Corrêa, J. T. B. Ferreira, Quezia B. Cass, Ellen M. Santangelo, Paulo H. G. Zarbin
Rok vydání:	2001
Předmět:	Chemistry Sex pheromone Organic Chemistry Botany Key (lock) PEST analysis Longhorn beetle Migdolus fryanus
Zdroj:	Synthetic Communications. 31:3685-3698
ISSN:	1532-2432 0039-7911
DOI:	10.1081/scc-100107019
Popis:	The four stereoisomers of N-2′-methylbutyl-2-methylbutylamide, the sex pheromone of the longhorn beetle Migdolus fryanus, an economically important pest of sugarcane in South America, were synthesized. The key intermediate 2-methylbutan-1-ol is commercially available only in its (S)-(−)-form. The (R)-(+)-enantiomer was obtained optically pure from methyl (S)-(+)-3-hydroxy-2-methylpropionate in five steps.
Databáze:	OpenAIRE
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