ChemInform Abstract: Diastereoselective Oxidative Carbon-Carbon Bond Formation via Silyl Bis-enol Ethers

Autor:	Leah C. Konkol, Charlotte L. Stern, Carla N. Taylor, Christopher T. Avetta, Karen C. Dugan, Regan J. Thomson
Rok vydání:	2009
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Range (particle radiation) chemistry Silylation Carbon–carbon bond Cyclohexanone Oxidative coupling of methane General Medicine Oxidative phosphorylation Enol Medicinal chemistry
Zdroj:	ChemInform. 40
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200919084
Popis:	Diisopropylsilyl bis-enol ethers are shown to be powerful intermediates for the diastereoselective dimerization and cross-coupling of cyclic ketones. The trends observed for the oxidative coupling of a range of different dialkylsilyl bis-enol ethers derived from cyclohexanone are rationalized by invoking a stereochemical model based on a Thorpe-Ingold effect.
Databáze:	OpenAIRE
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