THE SYNTHESIS AND STRUCTURE OF THE FIRST REPRESENTATIVES OF OLIGOARYLENEPHOSPHOCYCLANES

Autor:	E. I. Nifantyev, D. V. Gusev, Yu. I. Blokhin, Adam I. Stash, Vitaly K. Belsky
Rok vydání:	1995
Předmět:	Inorganic Chemistry chemistry.chemical_compound Stereospecificity chemistry Structure analysis Propane Organic Chemistry Diol Organic chemistry X ray analysis Biochemistry
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 102:143-154
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426509508042552
Popis:	Based on phenylphosphonous acid tetraethyldiamide and 2,2-di(p-oxyphenyl)propane diarylenecyclo-phenylphosphonite is synthesized. Its oxidation and sulfurization is investigated. It is shown that these reactions are stereospecific and lead to cis-isomers. The compounds obtained are the first representatives of oligoarylenephosphocyclanes. The structure of these compounds is confirmed by an X-ray structure analysis.
Databáze:	OpenAIRE
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