catena-Poly[[diaqua(1,4,7,10,13,16-hexaoxacyclooctadecane)barium(II)]-μ-cyano-[dicyanoplatinum(II)]-μ-cyano]

Autor:	Moses A. Lee, Jay R. Stork, Marilyn M. Olmstead
Rok vydání:	2005
Předmět:	Hydrogen bond chemistry.chemical_element Barium General Chemistry Decane Crystal structure Condensed Matter Physics Photochemistry Medicinal chemistry Metal chemistry.chemical_compound chemistry visual_art visual_art.visual_art_medium General Materials Science Platinum
Zdroj:	Acta Crystallographica Section E Structure Reports Online. 61:m1048-m1050
ISSN:	1600-5368
Popis:	The title compound, [BaPt(CN)4(C12H24O6)(H2O)2], contains a polymeric chain of alternating complexes of Ba2+ and Pt2+. A ten-coordinate Ba2+ complex results from coordination of the metal by 18-crown-6 and two water mol­ecules, and N-atom coordination by a cyano group of [Pt(CN)4]2− and by a second cis-related cyano group of a second [Pt(CN)4]2− generated by a crystallographic b-glide. Crosslinking via hydrogen bonds involving the remaining two cyano N atoms completes the crystal structure in the a and c directions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::01ec7205c90dddc19e51e1464d5e558c https://doi.org/10.1107/s1600536805013887 Zobrazit plný text záznamu Plný text ve formátu PDF