Solvent Effect in the Thermal Decomposition Reaction of trans-3,3-Dimethyl-5,6-tetramethylene-1,2,4-trioxacyclohexane

Autor:	Gladys Nora Eyler, L. F. R. Cafferata, Carmen M. Mateo, Elida Ester Álvarez, Adriana I. Cañizo
Rok vydání:	1999
Předmět:	chemistry.chemical_compound chemistry Trioxane Organic Chemistry Thermal decomposition Enthalpy Physical chemistry Entropy of activation Solvent effects Benzene Toluene Chemical decomposition
Zdroj:	The Journal of Organic Chemistry. 64:8457-8460
ISSN:	1520-6904 0022-3263
Popis:	The kinetic data of the thermal decomposition reaction of trans-3,3-dimethyl-5,6-tetramethylene-1,2,4-trioxacyclohexane has been measured in different solvents (benzene, toluene, 2-propanol, 2-methoxyethanol, and p-dioxane) at 0.02 mol kg-1 initial concentration and in the temperature range of 135.0−165.0 °C. The enthalpy and entropy of activation of the unimolecular reaction of this trioxane in several organic solvents have been correlated through “isokinetic relationships” to validate the existence of a genuine solvent effect on that reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::01c6d5d5eab641b8ea8441ed924b8d5b https://doi.org/10.1021/jo980658j Zobrazit plný text záznamu