Preparation of the Piperazine– and Triethylenediamine–Monoborane Adducts of BH3, BH2F, BHF2, and BF3

Autor:	J. M. Vanpaasschen, R. A. Geanangel
Rok vydání:	1975
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Displacement reactions Piperazine Base (chemistry) chemistry Diamine Organic Chemistry Polymer chemistry General Chemistry Catalysis Adduct
Zdroj:	Canadian Journal of Chemistry. 53:723-726
ISSN:	1480-3291 0008-4042
Popis:	The new compounds, triethylenediamine–BH2F, –BHF2, –BF3 and piperazine–BH2F, –BHF2, –BF3 have been isolated and characterized from the base displacement reactions involving the diamine and the trimethylamine–fluoroboranes. By this method only the monoborane adducts of the difunctional amines are formed. The stability of these monoborane adducts is rationalized from a mechanistic point of view. The proton and boron-11 n.m.r. and i.r. spectra are presented with the analytical results.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::01a419c4006cb1593e2a15141b8eda4f https://doi.org/10.1139/v75-101 Zobrazit plný text záznamu