ChemInform Abstract: Chiral Synthesis of Tri-O-methylimbricatine, an Etherified Derivative of the Starfish Alkaloid Imbricatine

Autor:	Julia Kubanek, Masaaki Imasho, Yoshikazu Nishimura, Tatsuya Fujii, Raymond J. Andersen, Masashi Ohba
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry biology Stereochemistry Alkaloid Methyl derivative Starfish Dermasterias Enantioselective synthesis General Medicine biology.organism_classification Derivative (chemistry)
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199843255
Popis:	A chiral synthesis of tri- O -methylimbricatine ( 2 ), the tri- O -methyl derivative of the unique benzyltetrahydroisoquinoline alkaloid imbricatine ( 1 ) isolated from the starfish Dermasterias imbricata , has been accomplished. As a result of the synthesis, the correctness of the structure and absolute stereochemistry proposed for imbricatine has been unequivocally confirmed.
Databáze:	OpenAIRE
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