| Autor: |
Abdoulaye Samake, Jean-Luc Jaffrezo, Olivier Favez, Samuël Weber, Véronique Jacob, Alexandre Albinet, Véronique Riffault, Esperanza Perdrix, Antoine Waked, Benjamin Golly, Dalia Salameh, Florie Chevrier, Diogo Miguel Oliveira, Jean-Luc Besombes, Jean M. F. Martins, Sébastien Conil, Géraldine Guillaud, Boualem Meshba, Benoit Rocq, Pierre-Yves Robic, Agnès Hulin, Sébastien Le Meur, Maxence Descheemaecker, Eve Chretien, Gaëlle Uzu |
| Rok vydání: |
2018 |
| DOI: |
10.5194/acp-2018-773 |
| Popis: |
A growing number of studies are using specific primary sugar species, such as sugar alcohols or primary saccharides, as marker compounds to characterize and apportion primary biogenic organic aerosols (PBOA) in the atmosphere. To better understand their annual cycles, as well as their spatio-temporal abundance in terms of concentrations and sources, we conducted a large study focusing on three major atmospheric primary sugar compounds (i.e. arabitol, mannitol and glucose) measured in various environmental conditions on about 5,300 filter samples collected at 28 sites in France. Our results show significant atmospheric concentrations of polyols (defined here as the sum of arabitol and mannitol) and glucose at each sampling location, highlighting their ubiquity. Results also confirm that polyols and glucose are mainly associated with the coarse rather than the fine aerosol mode. At nearly all sites, atmospheric concentrations of polyols and glucose display a well-marked seasonal pattern, with maximum concentrations from late spring to early autumn, followed by an abrupt decrease in late autumn, and a minimum concentration during wintertime. Such seasonal patterns support biogenic emissions associated with higher biological metabolic activities (e.g. sporulation, growth, etc.) during warmer periods. Results from a previous comprehensive study using Positive Matrix Factorization (PMF) based on an extended aerosol chemical composition dataset of up to 130 species for 16 of the same sample series has also been used in the present work. Results show that PBOA are significant sources of total OM in PM10 (13 ± 4 % on a yearly average, and up to 40 % in some environments in summer) at most of the investigated sites. The mean PBOA chemical profile is clearly dominated by OM (78 ± 9 % of the mass of the PBOA PMF factor on average), suggesting that ambient polyols are most likely associated with biological particle emissions (e.g. active spore discharge) rather than soil dust resuspension. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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