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In order to accurately assess the thermal maturity of highly/over-mature shales in Paleozoic strata in southern China, hydrothermal experiments of shale samples from the Dalong Formation from bed 18 of well-exposed Shangsi PTB Section was conducted in a semi-open system under various conditions of geological constraint. The saturated extracts of pyrolyzed shale samples were subjected to gas chromatography and mass spectrometry (GC-MS) analyses. The results indicated that hydrothermal experiments of Dalong shales in the presence of fluid pressure (FP), lithostatic stress (LS), water, catalyst of clay minerals and trace elements, is partially equivalent to catalytic hydropyrolysis in terms of the catalytic hydrogen effect for the release of bound biomarkers from geomacromolecules of kerogen and asphaltene. The evolutional trend of maturity-related biomarkers were classified into the following three categories: (a) the most common maturity parameters (e.g., Ts/(Ts + Tm) and C29S/(S + R)) initially increased and then decreased with a pyrolysis temperature (450 °C) at the reversal point during maturation; (b) the parameters (e.g., C32S/(S + R)) primarily increased or decreased and reached a temperature (400 °C) of tuning point, and then remained unaltered with increasing temperature (c) the parameters (e.g., C27DS/S); firstly increased, and then declined at a specific turning point temperature (425–500 °C), and thereafter continued to increase until the end of heating process. As a result, the threshold temperature for the release of bound sterane or terpane occurred in the range 400–500 °C. Most maturity-related sterane and terpane biomarker parameters cannot be applied to evaluate the maturity of highly/over-mature shale. However, the C30M/C30H ratio and S/T ratio, which are strongly correlated with temperature, may be employed to assess extremely mature shale from these Paleozoic strata due to the integrated effects of multiple factors in the thermal evolution process of biomarkers. This is very important for the exploration and development of shale gas in southern China. Additionally, the values of several source-related biomarker parameters derived from C27–29 regular steranes are relatively constant during maturation, such as the ternary plot of the C27–29 αααR sterane versus the C27/C29 αααR sterane ratio. These are useful indicators for distinguishing the genetic source of highly/over-mature shales. |
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