Sorption and selective properties of binary liquid-crystalline sorbent based on 4-Methoxy-4′-ethoxyazoxybenzene and a cetylated β-Cyclodextrin

Autor: E. A. Spiryaeva, L. A. Onuchak, T. S. Burmatnova, Yu. G. Kuraeva, Z. P. Belousova
Rok vydání: 2012
Předmět:
Zdroj: Russian Journal of Physical Chemistry A. 86:1308-1317
ISSN: 1531-863X
0036-0244
DOI: 10.1134/s0036024412080080
Popis: The mesomorphous, sorption, and selective properties of a binary sorbent based on achiral liquid crystal 4-methoxy-4′-ethoxyazoxybenzene and macrocyclic heptakis(2,3,6-tri-O-acetyl)-β-cyclodextrin (10.25 wt %) are investigated. Macrocyclic additive was found to induce the formation of a helically twisted nematic phase (N*). The standard and excess thermodynamic functions of sorption by binary sorbent from gaseous phase are determined for 29 organic compounds (n-alkanes, cycloalkanes, arenes, monoatomic alcohols, heterocycles, optical isomers of camphene, limonene, and butanediol-2,3). The investigated sorbent is found to have high structural selectivity over the wide temperature range of the N* mesophase (αp/m = 1.11–1.06, 95–120°C) and moderately expressed enantioselectivity within the narrow region of transition from the solid crystalline state to the N* mesophase (α+/− = 1.024–1.088, 91–100°C).
Databáze: OpenAIRE
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