Electrochemical Studies of LaCl3 and GdCl3 Dissolved in Fused LiCl‐KCl
| Autor: | Y. Berghoute, Frédéric Lantelme |
|---|---|
| Rok vydání: | 1999 |
| Předmět: |
Alkaline earth metal
Renewable Energy Sustainability and the Environment Chemistry Inorganic chemistry Refractory metals chemistry.chemical_element Condensed Matter Physics Electrochemistry Surfaces Coatings and Films Electronic Optical and Magnetic Materials Gibbs free energy symbols.namesake Transition metal Materials Chemistry symbols Lanthanum Cyclic voltammetry Molten salt |
| Zdroj: | Journal of The Electrochemical Society. 146:4137-4144 |
| ISSN: | 1945-7111 0013-4651 |
| DOI: | 10.1149/1.1392604 |
| Popis: | Molten systems are important as reaction media for the winning of strong oxidation or reducing elements such as fluorine, alkaline, and alkaline earth metals and aluminum. Recently, fused salt electrochemistry has been used for the preparation of refractory metals opening the way to the deposition of metals in solid state. The thermodynamic properties of solutions of lanthanum or gadolinium chlorides in mixed molten LiCl-KCl were determined by electromagnetic force (emf) measurements of LaCl{sub 3} or GdCl{sub 3} formation cells. The temperature dependence of the emf between 380 and 590 C was used to calculate the Gibbs energy and the enthalpy of formation of dissolved LaCl{sub 3} or GdCl{sub 3}. The electrode processes of La(III) and Gd(III) reduced on a tungsten electrode were investigated by cyclic voltammetry and chronopotentiometry. |
| Databáze: | OpenAIRE |
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