Indium-catalyzed reductive three-component coupling reaction of aliphatic/aromatic carboxylic acids with t-butyl mercaptan leading to unsymmetrical dialkyl sulfides
| Autor: | Norio Sakai, Shunsuke Yoshimoto, Takahiro Miyazaki, Yohei Ogiwara |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Sulfide 010405 organic chemistry Carboxylic acid Organic Chemistry Sulfidation Butyl mercaptan Reaction intermediate 010402 general chemistry 01 natural sciences Biochemistry Coupling reaction 0104 chemical sciences Catalysis chemistry Drug Discovery Polymer chemistry Organic chemistry Alkyl |
| Zdroj: | Tetrahedron Letters. 57:3117-3120 |
| ISSN: | 0040-4039 |
| DOI: | 10.1016/j.tetlet.2016.06.001 |
| Popis: | An InI3–TMDS (1,1,3,3-tetramethyldisiloxane) reducing system efficiently catalyzed a sequential three-component coupling of aliphatic carboxylic acids, aromatic carboxylic acids, and t-butyl mercaptan (t-butylthiol), to produce unsymmetrical dialkyl sulfides. With this reducing system, t-butyl mercaptan became a new source of sulfidation via an alkyl t-butyl sulfide that functioned as the reaction intermediate. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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