Reaction of ?-and ?-(trialkylsilyl)acroleins with a grignard reagent

Autor: V. A. Pestunovich, V. V. Keiko, M. G. Voronkov, Svetlana V. Kirpichenko, O. I. Randin
Rok vydání: 1978
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:372-374
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00923878
Popis: Reaction ofα- andβ-(trialkylsilyl)acroleins with methylmagnesium iodide forms the corresponding secondary unsaturated organosilicon alcohols. The reactions ofα-(trialkylsilyl)acroleins are accompanied by cleavage of the Si -C bond. The byproducts from β-(trialkylsilyl)aeroleins are primary unsaturated alcohols andα, β-unsaturated organosilicon ketones.
Databáze: OpenAIRE