Reaction of ?-and ?-(trialkylsilyl)acroleins with a grignard reagent
Autor: | V. A. Pestunovich, V. V. Keiko, M. G. Voronkov, Svetlana V. Kirpichenko, O. I. Randin |
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Rok vydání: | 1978 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:372-374 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00923878 |
Popis: | Reaction ofα- andβ-(trialkylsilyl)acroleins with methylmagnesium iodide forms the corresponding secondary unsaturated organosilicon alcohols. The reactions ofα-(trialkylsilyl)acroleins are accompanied by cleavage of the Si -C bond. The byproducts from β-(trialkylsilyl)aeroleins are primary unsaturated alcohols andα, β-unsaturated organosilicon ketones. |
Databáze: | OpenAIRE |
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