Spectroscopic Study of Electron Transfer in a Trifunctional Lysine with Anthraquinone as the Electron Acceptor

Autor: Dewey G. McCafferty, Sandra L. Mecklenburg, Bruce W. Erickson, Jon R. Schoonover, Thomas J. Meyer, Brian M. Peek
Rok vydání: 1994
Předmět:
Zdroj: Inorganic Chemistry. 33:2974-2983
ISSN: 1520-510X
0020-1669
DOI: 10.1021/ic00091a042
Popis: The transient properties of the redox-active amino acid dyads [Anq-Lys(Ru II b 2 m) 2+ -OCH 3 ](PF 6 ) 2 and [Boc-Lys(Ru II b 2 m) 2+ -NH-prPTZ](PF 6 ) 2 and the trifunctionalized amino acid [Anq-Lys[Ru II b 2 m) 2+ -NH-prPTZ](PF 6 ) 2 , where Anq is 9,10-anthraquinone-2-carbonyl, Lys is L-lysine, b is 2,2'-bipyridine, m is 4'-methyl-2,2'-bipyridine-4-carbonyl, and prPTZ is 3-(10H-phenothiazine-10)prpyl, were examined in CH 3 CN after nanosecond laser excitation
Databáze: OpenAIRE