Synthesis of Derivatives of closo-Dodecaborate Anion Based on Amino Acid Esters

Autor: K. Yu. Zhizhin, I. N. Klyukin, A. V. Burdenkova, N. A. Selivanov, Andrey P. Zhdanov, A. Yu. Bykov, N. T. Kuznetsov
Rok vydání: 2021
Předmět:
Zdroj: Russian Journal of Inorganic Chemistry. 66:1616-1620
ISSN: 1531-8613
0036-0236
Popis: Abstract This work proposes a new method for the synthesis of N-borylated amino acids based on nucleophilic substitution reactions in the [B12H11IPh]– anion. Esters of glycine and L-phenylalanine were used as nucleophiles. The structure of the products has been determined by multinuclear NMR spectroscopy, IR spectroscopy, and ESI mass spectrometry.
Databáze: OpenAIRE