Synthesis of Derivatives of closo-Dodecaborate Anion Based on Amino Acid Esters
Autor: | K. Yu. Zhizhin, I. N. Klyukin, A. V. Burdenkova, N. A. Selivanov, Andrey P. Zhdanov, A. Yu. Bykov, N. T. Kuznetsov |
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Rok vydání: | 2021 |
Předmět: | |
Zdroj: | Russian Journal of Inorganic Chemistry. 66:1616-1620 |
ISSN: | 1531-8613 0036-0236 |
Popis: | Abstract This work proposes a new method for the synthesis of N-borylated amino acids based on nucleophilic substitution reactions in the [B12H11IPh]– anion. Esters of glycine and L-phenylalanine were used as nucleophiles. The structure of the products has been determined by multinuclear NMR spectroscopy, IR spectroscopy, and ESI mass spectrometry. |
Databáze: | OpenAIRE |
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