Haloaldehyde Polymers. X. Poly(dibromochloroacetaldehyde)
| Autor: | Otto Vogl, D W Lipp |
|---|---|
| Rok vydání: | 1977 |
| Předmět: |
Polymers and Plastics
Chemistry technology industry and agriculture Cationic polymerization Chain transfer macromolecular substances Chain-growth polymerization Anionic addition polymerization Polymerization Polymer chemistry Materials Chemistry Precipitation polymerization Organic chemistry Ionic polymerization Living anionic polymerization |
| Zdroj: | Polymer Journal. 9:499-510 |
| ISSN: | 1349-0540 0032-3896 |
| DOI: | 10.1295/polymj.9.499 |
| Popis: | Dibromochloroacetaldehyde was synthesized in good yield from chloroacetaldehyde diethyl acetal by bromination. It was purified to give a monomer suitable for homo- and copolymerization. Polymerization could be carried out with anionic and cationic initiators; anionic polymerization gave good yields of a crystalline polymer which could be stabilized. Vacuum degradation of the polymer gave the monomer form quantitatively. The Tc of polymerization (1 M) was −40°C. Dibromochloroacetaldehyde copolymerized with chloral and phenyl isocyanate to insoluble and infusible polymer, but was less reactive than chloral. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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