The behaviour of medium-sized permethylated cyclosilanes towards SOCl2 and SOCl2-HC(OCH3)3

Autor:	Edwin Hengge, A. Spielberger, P. K. Jenkner
Rok vydání:	1992
Předmět:	Inorganic Chemistry Addition reaction chemistry.chemical_compound chemistry Organic Chemistry Materials Chemistry Organic chemistry Orthoester Physical and Theoretical Chemistry Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 427:161-164
ISSN:	0022-328X
DOI:	10.1016/0022-328x(92)83081-r
Popis:	Treatment of Si6Me12 with SOCl2 in various solvents gives α,ω-dichloropermethylpolysilanes (nSi = 2,3,4,6) at temperatures above 80°C. In contrast to an earlier report, treatment of the α,ω-dichloropermethylpolysilanes with HC(OCH3)3 in the presence of SOCl2 does not give Si6Me12.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::00e1e453102575af67f5f1ad87df5d68 https://doi.org/10.1016/0022-328x(92)83081-r Zobrazit plný text záznamu