Synthesis and reactions of some new thiocarboxamido complexes of manganese and molybdenum carbonyls
| Autor: | W. K. Dean, Paul M. Treichel |
|---|---|
| Rok vydání: | 1974 |
| Předmět: |
inorganic chemicals
Ligand Organic Chemistry chemistry.chemical_element Metal carbonyl Manganese Photochemistry Biochemistry Sulfur Inorganic Chemistry Metal chemistry.chemical_compound chemistry Molybdenum visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Triphenylphosphine Carbon |
| Zdroj: | Journal of Organometallic Chemistry. 66:87-93 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)93891-9 |
| Popis: | Several thiocarboxamido complexes of manganese and molybdenum have been prepared by the reactions of metal carbonyl anions with dimethylthiocarbamoyl chloride, Me2NCSCl. In these complexes the thiocarboxamido group is thought to be bound to the metal through both the carbon and sulfur atoms, acting as a three-electron donating ligand. The sulfur atom can be methylated without altering this mode of bonding. Reactions of some of these complexes with triphenylphosphine are described. |
| Databáze: | OpenAIRE |
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