Synthetic studies directed toward streptenol D: enantioselective preparation of the 3,5-diacetoxy-6E,8E-decadiene segment
Autor: | William A. Donaldson, Bireshwar Dasgupta |
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Rok vydání: | 1998 |
Předmět: | |
Zdroj: | Tetrahedron: Asymmetry. 9:3781-3788 |
ISSN: | 0957-4166 |
Popis: | The enantioselective preparation of 2-(3′ R ,5′ R -diacetoxy-6 E ,8 E -decadienyl)-1,3-dioxane, (+)- 13 , is described. This synthesis of the skeleton of streptenol D utilizes the ability of a diene-complexed (tricarbonyl)iron unit to serve as a protecting and stereodirecting functionality. |
Databáze: | OpenAIRE |
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