Fast analysis of derivatives of polycyclic aromatic hydrocarbons in soil by ultra-high performance supercritical fluid chromatography after supercritical fluid extraction enrichment
| Autor: | Jing Xie, Yehua Han, Limin Ren, Yanfen Zhang, Ying-Hao Wang, Cheng-Long Dong, Wen Zhou, Yu-Chi Zhang |
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| Rok vydání: | 2021 |
| Předmět: |
Detection limit
chemistry.chemical_classification Chromatography Supercritical fluid extraction Energy Engineering and Power Technology Polycyclic aromatic hydrocarbon Geology Repeatability Geotechnical Engineering and Engineering Geology Volumetric flow rate Geophysics Fuel Technology chemistry Geochemistry and Petrology Phase (matter) Supercritical fluid chromatography Economic Geology Ultra high performance |
| Zdroj: | Petroleum Science. 18:1860-1866 |
| ISSN: | 1995-8226 |
| Popis: | An efficient and environment-friendly method for simultaneous determination of 13 typical derivatives of polycyclic aromatic hydrocarbon (PAH) in petroleum-polluted soil with nitro-, oxy- and alkyl-functional group was developed using supercritical fluid extraction (SFE) followed by ultra-high performance supercritical fluid chromatography (UHPSFC). Parameters of UHPSFC, including type of stationary phase and mobile phase modifiers, gradient elution process, backpressure, column temperature, and the flow rate of mobile phase, were systematically optimized, achieving a fast separation within 4.2 min. Limits of detection (LOD) were 0.005–0.1 μg mL−1 or 0.1–2.0 ng g−1, respectively, with a good repeatability (RSD |
| Databáze: | OpenAIRE |
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