Preparation of glycosyl disulfides and sulfides via the formation of glycosyl Bunte salts as thiol surrogates
| Autor: | Anup Kumar Misra, Monalisa Kundu |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
animal structures 010405 organic chemistry Aryl Organic Chemistry Disulfide bond macromolecular substances 010402 general chemistry 01 natural sciences Biochemistry High yielding 0104 chemical sciences carbohydrates (lipids) Bunte salt chemistry.chemical_compound chemistry Sodium sulphide Drug Discovery Polymer chemistry Thiol lipids (amino acids peptides and proteins) Glycosyl |
| Zdroj: | Tetrahedron. :132242 |
| ISSN: | 0040-4020 |
| DOI: | 10.1016/j.tet.2021.132242 |
| Popis: | A convenient odourless reaction condition has been developed for the preparation of symmetrical glycosyl disulfide derivatives and aryl glycosyl disulfide derivatives from corresponding glycosyl iodides via in situ formation of glycosyl Bunte salts as thiol surrogates. The reaction has been further extended towards the preparation of glycosyl sulfides derivatives from corresponding Bunte salt in the presence of sodium sulphide. Most of the reactions were high yielding and suitable for scaling up. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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