Employing tetrahedral {Zn 4 O} clusters as building subunits to construct a new acentric metal–organic framework

Autor:	Chonghui Zhang, Zongwu Wei, Xianzhong Bu, Shaofeng Ren
Rok vydání:	2014
Předmět:	Inorganic Chemistry Diffraction Crystallography Group (periodic table) Chemistry Acentric factor Materials Chemistry Tetrahedron Hydrothermal synthesis Metal-organic framework Physical and Theoretical Chemistry Schläfli symbol Luminescence
Zdroj:	Inorganic Chemistry Communications. 48:158-160
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2014.08.017
Popis:	Hydrothermal reaction of H3L and Zn(NO3)2 produced a new noncentrosymmetric Zn(II) compound, namely [Zn4(μ4-O)(L)2(H2O)3]n (1 H3L = biphenyl-3,4,5-tricarboxylic acid). Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the acentric Pna21 space group and features a 3D framework based on isolated tetrahedral {Zn4O} clusters as building subunits. Topological analysis reveals that it can be simplified into a 3-nodal (3,3,6)-connected topological network with the Schlafli symbol of {4·62}2{42·67·86}. In addition, the nonlinear optic and luminescent properties of this compound were also investigated at room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::00af3e70b5d70a2ea6be48f7be392ee4 https://doi.org/10.1016/j.inoche.2014.08.017 Zobrazit plný text záznamu Full Text from ScienceDirect