On the Mixed Crystals Formation in the Fe(Zn) (HCOO)2–Cd(HCOO)2–H2O System

Autor:	Violeta Z. Vassileva
Rok vydání:	1996
Předmět:	biology Inorganic chemistry General Chemistry Crystal structure Condensed Matter Physics Bond length chemistry.chemical_compound Crystallography chemistry Octahedron biology.protein General Materials Science Carboxylate Isostructural Hydrate Solid solution Organic anion
Zdroj:	Crystal Research and Technology. 31:993-1000
ISSN:	1521-4079 0232-1300
Popis:	The solubility in the Fe(HCOO) 2 -Cd(HCOO) 2 -H 2 O and Zn(HCOO) 2 -Cd(HCOO) 2 -H 2 O systems have been studied by the method of physico-chemical analysis at 25 °C and mixed crystals of the type Fe 1-x cd x (HCOO) 2 .2H 2 O and Zn 1-x Cd x (HCOO) 2 .2H 2 O have been obtained. The lattice parameters of the mixed crystals have been calculated. It has been established that the isostructural Fe(HCOO) 2 .2H 2 O and Cd(HCOO) 2 .2H 2 O form isomorphous mixed crystals, whereas the isostructural Zn(HCOO) 2 .2H 2 O and Cd(HCOO) 2 .2H 2 O yield isodimorphous mixed crystals. The difference in the behaviour of the two pairs of formate salts has been attributed to the difference in the Me-O m bond lengths in the coordination octahedra, forming the crystal structures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::00ac5a4714ed5143c051a33c94b1179c https://doi.org/10.1002/crat.2170310806 Zobrazit plný text záznamu Plný text