The crystal structure and electrical/thermal transport properties of Li1−xSn2+xP2and its performance as a Li-ion battery anode material
| Autor: | Akira Miura, Yosuke Goto, Takeshi Mito, Hidetomo Usui, Yusuke Nakai, Tatsuma D. Matsuda, Yuji Aoki, Kiyoshi Kanamura, Yoshifumi Nakacho, Yoshikazu Mizuguchi, Chikako Moriyoshi, Shota Nakanishi, Yuto Yamada, Yoshihiro Kuroiwa |
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| Rok vydání: | 2021 |
| Předmět: |
Superconductivity
Materials science Renewable Energy Sustainability and the Environment Analytical chemistry 02 engineering and technology General Chemistry Electronic structure Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences Ion Anode Electrical resistivity and conductivity General Materials Science 0210 nano-technology Ternary operation |
| Zdroj: | Journal of Materials Chemistry A. 9:7034-7041 |
| ISSN: | 2050-7496 2050-7488 |
| Popis: | A new ternary layered pnictide, Li1−xSn2+xP2, was synthesized by a solid-state reaction and its properties were examined to explore its potential as a multifunctional material. The compound crystallizes in a layered structure in the Rm space group (no. 166) with buckled honeycomb Sn–P layers separated by mixed-occupation Li/Sn layers. Crystal structure analysis by synchrotron X-ray diffraction showed that the substitution degree of Li by Sn is x = 0.38. The local ordering of Li/Sn occupation was demonstrated using 31P nuclear magnetic resonance analysis. The thermal and electrical transport properties are significantly affected by this local ordering. The lattice thermal conductivity of Li1−xSn2+xP2 was found to be relatively low (1.2 W m−1 K−1 at 525 K). The room-temperature electrical resistivity of Li1−xSn2+xP2 was found to be 0.3–0.4 mΩ cm and metallic conductivity was observed down to 0.5 K. First-principles calculations demonstrated that the electronic structure and Fermi energy of Li1−xSn2+xP2 are significantly dependent upon x. Moreover, the electronic structure of Li1−xSn2+xP2 is different from that of the related compound NaSn2As2, which shows a superconducting transition. Electrochemical measurements using a single-particle technique demonstrated the activity of Li1−xSn2+xP2 as an anode material for rechargeable Li-ion batteries. |
| Databáze: | OpenAIRE |
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