CO oxidation on MgAl2O4 supported Irn: activation of lattice oxygen in the subnanometer regime and emergence of nuclearity-activity volcano

Autor: Yubing Lu, Coogan Thompson, Chun-Te Kuo, Xiwen Zhang, Adam S. Hoffman, Alexey Boubnov, Simon R. Bare, Libor Kovarik, Hongliang Xin, Ayman M. Karim
Rok vydání: 2022
Předmět:
Zdroj: Journal of Materials Chemistry A. 10:4266-4278
ISSN: 2050-7496
2050-7488
DOI: 10.1039/d1ta09740g
Popis: Ir subnanometer clusters activate surface oxygen on a traditionally non-reducible MgAl2O4 support which leads to a more active two-site mechanism during low-temperature CO oxidation.
Databáze: OpenAIRE